Generally plastics are electrically insulating.
Infact, their insulation properties have made them ideally suitable
for wire, cable as well as several other electrical applications.
There are however newer applications wherein Plastics' insulating
properties are a liability.
Due to an intensive usage of electronics in consumer
products and increasing miniaturization of products, a need to protect
these parts from Electrostatic Dissipation
(ESD) and Electromagnetic Interference (EMI)
shielding arises. An increasing shift to electrostatic painting
of automotive and industrial parts require paintable plastic products,
which in turn demands plastic materials to be electrically conductive.
The conductive thermoplastic market in North America has reached
a level of 225 Kt in 2001. It is expected to grow at about 8-10%
in the next 5 years.
Thermoplastic compounders have obtained better conductivity by
incorporating Carbon black, Carbon fibers, Aluminium flakes or Stainless
Steel fibers. Newer polymers with intrinsic capability of conductivity
are being developed. These polymers with different degree of conductivity
are known as Inherently Conductive Polymers
(ICP) or Inherently Dissipative Polymers (IDP).
Electrical Conductivity Range |
Type |
Surface Resistivity, OHM/Sq
mm |
INSULATION |
>1012 |
ANTISTATIC |
109-1011 |
Electrostatic
Dissipation (ESD) |
104-106 |
Electromagnetic
Interferene (EMI) |
101 - 102 |
CONDUCTIVE |
<101 |
They are very efficient in creating conductive networks when alloyed
with a conventional thermoplastic polymer. The most commonly known
ICP is Polyaniline, manufactured by Panipol of Finland. IDPs are
generally elastomers that contain "charge carrying blocks".
These blocks have the ability to conduct electricity. The IDP polymer
range developed by Noveon (BF Goodrich, formerly) can be used in
the matrix of Styrenics, PETG and PP. In recent years, several compounders
like DSM, Lati, LNP and RTP have developed IDP based compounds with
surface resistivity ranging from 103-1011
ohm/sq mm.
Carbon black, so far is the workhorse for conductive plastics business
due to its low cost. However, it has two major limitations. Carbon
black can only provide black colour. Other colours are extremely
difficult to produce, if not impossible. Carbon black can also damage
sensitive microelectronic devices.
ICP and IDP based conductive products are very efficient in conductivity
and are more amenable to colouring. Another development is of very
efficient carbon nano-tubes or nano-fibres which can impart high
conductivity at lower loadings. Their usage is presently limited
because of prohibitively higher cost. However nano-carbons are expected
to prove indispensable in future. These nano-carbons are supplied
by Mitsui and Showa Denko from Japan and Hyperlon catalysts from
USA. For improved dispersion, some of the suppliers like Hyperlon
provide them in the form of masterbatches. They are quite efficient
and require less than 50% loading compared to carbon black.
A new type of carbon fiber from pitch developed by Conoco is expected
be more efficient than carbon fibers based on PAN.
To eliminate colorability problem of carbon black, stainless steel
fibers are widely used, particularly in cell phones, etc to avoid
electromagnetic interferences.
The options for achieving electrical conductivity are indeed increasing
in this growing market.
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