Thermoforming is restricted to relatively simple shapes having
limited depth of draw. It is easy to thermoform articles having
section thickness less than 1.0 mm, whether it is large area articles
like refrigerator liners or smaller articles like thin wall disposable
cups, which are otherwise difficult to injection mould.
In thermoforming, the mould and machine costs
are quite low as compared to injection moulding. The thermoforming
moulds as compared to injection mould are lighter in weight and
easy to install on the machine. They are easy to fabricate and
that to in a shorter period of time. In thermoforming the starting
material is sheet and after forming a sheet, secondary trimming
operation is carried out to get the finished article. This will
generate nearly more than 35% of the sheet scrap.
The major thermoplastic raw materials used for thermoforming of
thin wall containers are:
Characterstics of major thermoplastic materials used for thermoforming of thin
wall containers
Materials
|
Characteristics |
Applications |
HIGH
IMPACT POLYSTYRENE (HIPS) GRAFT CO-POLYMER |
*TRANSLUCENT
TO OPAQUE
*EASY TO THERMOFORM
*WATER VAPOUR AND OXYGEN PERMEABILITY HIGHER THAN
POLYOLEFINS
*IT CAN BE DIRECTLY PRINTED WITHOUT ANY SURFACE
TREATMENT
*FDA APPROVED GRADES AVAILABLE
*RECYCLABLE
*THERMOFORMING TEMPERATURE IS 130°c - 150°c
*GOOD LOW TEMPERATURE RESISTANCE (AS COMPARED TO
PP)
*HIGH GLOSS GRADES AVAILABLE
|
PACKAGING
APPLICATIONS; PACKAGING OF ICE-CREAM, CURDS, YOGHURT, DAIRY
SWEETS, MARGARINE, BEVERAGE, GLASSES, PLATES, INSERT TRAYS
FOR BISCUITS AND CHOCOLATES, FRUIT SQUASHES FOR A SHORT SHELF-LIFE,
ETC.
|
STYRENE-BUTADIENE
BLOCK CO-POLYMER HIPS |
*TRANSPARENT HIPS
*SUPERIOR GLOSS
*OTHER CHARACTERISTICS SIMILAR TO HIPS |
FRUIT
BOXES, CAKE AND CONFECTIONARY BOXES, BEVERAGE GLASSES, LUNCH
BOXES, BLISTER PACKING ETC. GOOD FOR BLISTER PACKING |
BIAXIALLY
OR ORIENTED POLYSTYRENE SHEETS (BOPS/OPS) |
*EXCELLENT TRANSPARENCY
*GOOD MECHANICAL/IMPACT STRENGTH
*THERMOFORMING
AT TEMPERATURE AROUND 110°c
|
POTENTIAL
REPLACEMENT FOR PVC APPLICATIONS, SUCH AS INSERT TRAYS FOR BISCUITS,
CHOCOLATES, ETC. CAKE CONTAINER, FRUIT BOXES, BLISTER PACKING,
GOOD FOR BLISTER PACKING |
FOAMED
POLYSTYRENE |
FOAMED POLYSTYRENE SHEET HAVING DENSITY 65 KG/M.SQ. TRAYS FOR
FRUIT PACKING FORMED FROM SHEETS HAVING THICKNESS 2 TO 3 MM.
FOAMED TRAYS ARE:
- STIFF
- DOES NOT ABSORB WATER
- CAN BE DEEP FROZEN
- DOES NOT CATCH FUNGUS
- DOES NOT GET SPOILED IF ANYTHING SPILLED
OVER IT |
GOOD
FOR FRUIT PACKING LIKE APPLE ETC. FOR EXPORT. GOOD FOR PACKING
TOMATO. ALSO FOR FAST FOOD CHAIN BURGER TRAY, PIZZA, TRAY, ETC. |
POLYPROPYLENE |
*GOOD HEAT RESISTANCE
*NOT EASY TO THERMOFORM AS COMPARED TO HIPS
*TRANSLUCENT (CLARIFIED GRADES IMPROVE TRANSPARENCY)
*LOW TEMPERATURE IMPACT STRENGTH, JUST ADEQUATE
*SURFACE TREATMENT IS NECESSARY FOR PRINTING
*'LIVE-HINGE' POSSIBLE
*EXCELLENT FAT RESISTANCE
*WATER VAPOUR AND OXYGEN PERMEABILITY LESS THAN
HIPS
*FDA APPROVED GRADES AVAILABLE
*RECYCLABLE |
FOR
PACKAGING OF YOGHURT, DAIRY SWEETS, MARGARINE, MINERAL WATER
ETC. DISPOSABLE BEVERAGE GLASSES, PLATES, ETC.
GOOD
FOR MICROWAVE OVENABLE HEATING TRAYS. INSERT TRAYS FOR BISCUITS,
CHOCOLATES, ETC. GOOD FOR BLISTER PACKING
|
PVC |
*TRANSPARENCY
*EASY TO THERMOFORM
*LIABLE FOR THERMAL DEGRADATION
*LOW HEAT RESISTANCE
*EASY TO PRINTING WITHOUT SURFACE TREATMENT
*ENVIRONMENT PROBLEM |
EXCELLENT
FOR BLISTER PACKING PORTION PACKS FOR JAM, ETC. MARGARINE TUBS.
INSERT TRAYS FOR BISCUITS, CHOCOLATES ETC. |
PET (POLYETHYLENE TEREPHTHALATE) |
*UNIQUE ABILITY TO EXIST IN BOTH THE FORMS - CRYSTALLINE
AND AMORPHOUS
*CPET CAN WITHSTANDTEMPERATURE UPTO 220°C
WHILE PET CAN UPTO 70°C. THEY CAN
WITHSTAND TEMPERATURE AS LOW AS
- 40 DEG.C.
*PET IS TRANSPARENT WHILE CPET IS OPAQUE
*THEY HAVE GOOD IMPACT STRENGTH AND
IMPERMEABILITY TO GASES AND
BETTER FAT RESISTANCE
*THEY ARE RECYCLABLE OR CAN BE HYDROLYSED
BACK TO ORIGINAL STARTING CHEMICALS
* THEY ARE FDA APPROVED |
CPET
TRAYS ARE DUAL-OVENABLE, CAN BE USED IN MICROWAVE AND CONVENTIONAL
OVENS. THEY ARE USED FOR PROCESSED FOODS. A PET USED AS A REPLACEMENT
FOR PVC APPLICATIONS. GOOD FOR BLISTER PACKING, DRINKING GLASSES,
ETC. FRESH GOURMET FOOD UP MARKET CONTAINERS |
Out of all the above thermosplastic materials, high impact polystyrene
is easy to thermoform. ABS sheets also thermoform better but they
should not be overheated otherwise on forming they may blister off
and may give rough surface. Unfilled polypropylene, because of its
partly crystalline structure and definite melting point is comparatively
difficult to thermoform while filled polypropylene having better
stiffness property relatively thermoform better. Multilayer sheets
also can thermoform good.
The choice of each material depends upon the end-use requirement
and its cost. The most important properties required particularly
in the case of rigid packaging are:
 |
Stiffness and ductility of the material. |
 |
Easy processability - thermoforming / Injection moulding etc. |
 |
Maximum wall thickness permissible in the article or the weight
of the article. |
 |
Cooling cycle during forming and moulding. |
 |
Permeability of gases and water vapour or the required shelf-life
of the product to be packed. |
 |
Compatibility of the product to be packed with the plastic material. |
 |
Heat resistance of the plastic materials. |
 |
Ease at which the plastic containers can be printed by dry offset
process for four or six colours printing. |
 |
Whether plastic containers are sterilisable. |
 |
Economic consideration. |
No single thermoplastic material can satisfy all these properties.
Out of all the thermoplastics, high impact polystyrene can satisfy
most of the properties except impermeability of oxygen and water
vapour. Polypropylene is to an extent better than HIPS in impermeability
of water vapour and heat and chemical resistance but not that good
in case of oxygen impermeability.
The introduction of five layer multilayer sheets like HIPS/EVOH/HIPS
or HIPS/EVOH/PP or HIPS/PVDC/PP or PP/EVOH/PP etc. help in improving
the impermeability of gases. The extruded block copolymer or GPPS/HIPS
sheet give glossy surface on the matt surface of HIPS and also can
give two colour sheet - bright colour on the outside and white colour
in the inside of the cups thermoformed from such sheet.
Thin wall cups, tubs etc.
There is an increasing demand for thin wall disposable cups, tubs
etc. for packaging of food, especially milk products. The preferred
materials are Polystyrene, PVC and Polypropylene. The selection of
the processing technique depends upon important properties of the
materials like stiffness, permeability of gases and water vapour,
transparency, etc. The selection of the material also depends upon
the price of the material, minimum wall thickness permissible in the
cup, weight of the cup, cooling cycle during forming and the desired
quality of the cup. The stiffness of the material is expressed by
the modulus of elasticity of the material. By the thermoforming process,
it is possible to bring down the wall thickness and weight of the
cup to a minimum possible limit with acceptable impact and stiffness
property. In stiffness property, PVC works out as a better material
and polystyrene is comparable to it while polypropylene is inferior
to both of them. The cooling time-cycle depends upon the wall thickness
and weight of the cup.
The thin wall thermoformed cups first came on the market in the year
1950. The cups were produced on a roll fed sheet thermoforming line.
In the year 1960 it was brought out that in line sheet extrusion and
thermoforming equipment will help in producing thin wall cups from
transparent general purpose polystyrene, which otherwise is not possible
because of its brittleness. But the 1974 oil crisis accelerated the
development of in line sheet extrusion - thermoforming equipment.
The oil crisis increased the prices of the plastic raw-materials and
the cost of the energy and the need of the hour was to conserve energy.
This led to the development of in line sheet extrusion - thermoforming
equipment which were desplayed first time by the world's three leading
manufacturers in K-75 Dusseldorf fair. These lines save the evergy
by 30% and utilise the material efficiently and gave out cups at a
very high output rates. It also overcame the problem of uniformly
heating the sheet particularly in polypropylene because of its low
thermal conductivity. All the products which can be thermoformed on
sheet fed lines can be formed on in line thermoforming process. Therefore,
in-line sheet extrusion thermoforming technique offers the best economics
as there is a saying in the energy cost;(as high as 30 to 40%) the
output rates are very high, the scrap generated is recycled and there
is hardly any loss in the material. As setting time of the line is
long and more scrap is generated the line is good only if it run is
long and frequent changes of the moulds are not desired.
Trays
The trays for confectionery products are thermoformed from HIPS/PP/APET
thin gauge sheets. They can be transparent, coloured or translucent
and mostly used as insert trays.
The roll fed sheet lines are popular all over the world for thermoforming
of trays. These lines are suitable for all the materials like Polystyrene
and Polypropylene. These lines have an advantage that they can use
multilayer sheets.
Material like OPS sheets pressure formed at 110°C for trays for salad
or for cake packaging.
The roll fed sheet therforming line for thin wall cups, tubs or confectionery
trays can handle materials like HIPS,PP,PET, Multilayer sheets etc.
The sheet reels normally handed having width ranging from 150 mm to
495 mm and can take up the material rolls up to 1200 mm dia. The machine
forms the sheet by plug assist technique in case of cups and tubs
and straight thermoforming in case of trays having multlicavity female
moulds. The sheets are heated for thermoforming by infrared ceramic
sandwich type heaters, so that they are brought to the forming temperature
fast and can give forming cycle as high as 35 to 40 cycles per minute.
In case of PP as it takes longer heating-up time a preheater is provided
prior to sandwich heating system in order to get faster forming cycle.
The heater unit is equipped with rows of ceramic heater elements and
they are controlled iln longitudinal direction, through thermocouple.
This keep the temperature fluctuation at the mimimum over the entire
area. The maximum depth of draw which can be taken on forming is 100mm.
The mould is so designed that the cup, the tub and the trays can be
formed and punched in place. The mould may be cooled by chilled water.
There are machines available which can give output of 10000-100000
cups or tubs or trays per hour. Roll fed sheet thermoforming lines
are more flexible than in-line sheet and thermoforming lines as the
moulds can be changed frequently and short run for any shape and size
is possible, only the scrap generated required to be recycled.
Solid phase pressure forming
Polypropylene, because of its low melt strength at thermoforming
temperature is better thermoformed just below its crystalline melting
point of 167°C - which is around 160°C + 2°C. The process involves
female tooling with plug assisted pressure forming. PP pellets, usually
of MFI 2 to 3 g/10 mts. (230°C/2.16 kg) are extruded into 0.25 to
2.0 mm thick sheet and then fed through the heating unit to the pressure
former and thermoformed.
Dual ovenable tray
The dual ovenable tray are CPET tray and can withstand temperature
from - 40° to + 220°C. It is thus excellent for use in freezer, micro
waves and conventional electrical ovens.
While PP tray can withstand temperature from - 20° to + 120°C and
therefore it is good for use in freezer and microwave oven and not
conventional electrical oven.
The APET tray can withstand temperature from - 40°C to +65°C, therefore
it is neither used for microwave nor for conventional ovens.
Conclusion
Today a number of food processing industries have come up in the
country and they need the right type of packaging materials. The
dairy industry is expanding at a faster rate and the demand for
the plastic packing materials is increasing by many times. The indigenous
machine manufacturers have also come out with thermoforming machines
needed to form the thermoplastic sheets for the packaging industry.
The thermoplastic sheet manufacturers have started developing multilayer
sheets. Therefore, during the coming decade our country will witness
the excellent development taking place on the thermoforming front.
BY SURESH S. JHAVERI
|