After reading our recent article
on 'New developments continue to expand and strengthen applications
of Polypropylene'. Some of the readers showed an interest
in learning about the new PP grades that can help them to make their
products better. We, from Plastemart.com, like to highlight some
of the recently introduced grades.
Blown Films
PP due to its poor melt strength
compared to PE has a very limited role in the conventional
upward extrusion film blowing. While some commercial success
was observed with Basell's catalloy products in the last decade,
new grades have emerged from Dow Atofina.
Dow's Inspire High melt strength(HMS) grades have improved
processability. They offer 20 times greater melt strength
compared to conventional PP. These grades also have better
drawability (almost 3 times more) compared to the conventional
PP grades. Two grades called Inspire 112 and D114 with 0.4
MFR and 0.5 MFR respectively provide more than 120 gram dart
impact on 50 micron film. The PP bags made from Inspire 112
have excellent autoclavability due to higher melting point.
Both these grades offer an opportunity for retort pouches.
They can also be used in melt phase thermoforming sheets.Atofina
has also recently introduced high melt strength grades called
Finaplas 1251 for blown films. This MPP grade is expected
to provide good clarity (haze value of 5 - 7%). Atofina has
also been offering a high crystalline polymer grade 3270 with
improved processability. It also provides excellent stiffness.
Cast BOPP Films
Atofina has been offering
metallocene (mPP) grade Finaplas 1571 with 10 MFR having low
haze value of 4-6.A very interesting functionalised mPP grade
SM 7-vol that is grafted ith maleic anhydride layer for film.
This grade can improve compatability of PP ith ABS, PC or
even TPU. Of course Basell's Clyrell random copolymers have
low scale initiation temperatures. Their organoleptics due
to low level of hexane extractables make them ideal for coating
layers of BOPP film.Chevron Phillips is offering enhanced
homopolymer grades HGY 020 and HGY 030 ith 2 & 3 MFR respectively
for high speed BOPP lines. Both of them improve running speeds
by almost 25% compared to the conventional BOPP grades. ExxonMobil
is also offering an easy processable homopolymer grade PP4792E1.
It also has haze value lower than 1% and excellent gloss.
Corrugated Sheet
BP has introduced
Accturf 3140 homopolymer with 1.3 MFR that has long term thermal
stability and improved printability.
Optical Fiber Conduit
Dow's Inspire D 113-01 impact
copolymer with 0.9 MFR has excellent low temperature impact
and is aimed at optical fiber conduits. Will it replace MDPE/HDPE
that is commonly used for this application.
Wire & Cable
Equistar from
USA is offering an impact copolymer grade PP 4173S using Novolen
technology. This grade can be used for high speed cable extrusion
without affecting centring of conductor. It meets Telecordia
017 aging requirement. It can be used as a solid insulation
or as skin layer over HDPE foam insulation and provides more
mechanical strength.
Injection Moulding
There are several grades developments in this largest application
segment. These grades fall in the category of heterophasic
impact copolymers. Most of these developments have been
aimed at enhanced rigidity-impact balance. Some of them
are aimed to improve heat resistance.
Some of the newer grades for injection moulded products
are:
Sr. No. |
Company |
Types of grades |
MFR |
Characteristics / Applications |
1 |
Atofina |
Finplas 1751(mPP) |
25 |
High Flow |
2 |
Basell |
Clyrell impact copols. |
|
Clarity, gloss, toughness |
|
|
Metocene X 50182(mPP) |
18 |
High stiffness, low warpage |
|
|
Metocene X 70293(mPP) |
40 |
Excellent clarity & improved toughness |
|
|
Metocene X 50081(mPP) |
60 |
Nulcleated for fast cycling thin walled
parts |
|
|
Metocene X 50109(mPP) |
60 |
3 |
ExxonMobil |
Achieve 1654(mPP) |
Low |
small medical & electronics parts |
|
|
Achieve 1635E1(mPP) |
28 |
clarified homopolymer for fast cycling clear article
|
|
|
Achieve 1605(mPP) |
32 |
High HDT |
|
|
Achieve 1615 (mPP) |
34 |
Nucleated with high HDT |
In addition, several newer grades are available from BP,
Chevron Phillips, Equistar and Huntsman. Their information
can be obtained by viewing their websites or contacting
their marketing office. This report does not include all
the new developmental grades, but provides a window to look
at some exciting products.
|